{N′-[1-(5-Bromo-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2N′,O}dibutyltin(IV)
نویسندگان
چکیده
منابع مشابه
{N′-[1-(5-Bromo-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2 N′,O}dibutyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. Both butyl chains and the naphth-yl-oxy portion are disordered over two sets of sites of equal occupancy.
متن کاملDicyclohexyl{3-hydroxy-N′-[1-(2-oxidophenyl-κO)ethylidene]-2-naphthohydrazidato-κ2 N′,O}tin(IV)
In the title compound, [Sn(C(6)H(11))(2)(C(19)H(14)N(2)O(3))], the Sn(IV) atom is O,N,O' chelated by the deprotonated Schiff base ligand and exists in a cis-trigonal-bipyramidal environment, completed by the two cyclohexyl ligands.
متن کامل[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dimethyltin(IV)
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond between the amido N atom and hydr-oxy H atom in the Schiff base ligand helps to stabilize the overall mol-ecular structure.
متن کامل[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dibutyltin(IV)
The Sn(IV) atom in the title compound, [Sn(C(4)H(9))(2)(C(18)H(11)BrN(2)O(3))], shows a distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination. One of the butyl chains is disordered over two sites in a 0.60 (1):0.40 (1) ratio.
متن کامل[N′-(5-Bromo-2-oxidobenzylidene-κO)-3-hydroxy-2-naphthohydrazidato-κ2 N′,O]dicyclohexyltin(IV)
The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclo-hexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s160053680902457x